全文获取类型
收费全文 | 48314篇 |
免费 | 2757篇 |
国内免费 | 153篇 |
学科分类
工业技术 | 51224篇 |
出版年
2023年 | 537篇 |
2022年 | 328篇 |
2021年 | 1391篇 |
2020年 | 1071篇 |
2019年 | 1175篇 |
2018年 | 1432篇 |
2017年 | 1411篇 |
2016年 | 1751篇 |
2015年 | 1294篇 |
2014年 | 2090篇 |
2013年 | 3007篇 |
2012年 | 3265篇 |
2011年 | 3893篇 |
2010年 | 2815篇 |
2009年 | 2923篇 |
2008年 | 2814篇 |
2007年 | 2185篇 |
2006年 | 2034篇 |
2005年 | 1723篇 |
2004年 | 1571篇 |
2003年 | 1513篇 |
2002年 | 1329篇 |
2001年 | 1134篇 |
2000年 | 901篇 |
1999年 | 839篇 |
1998年 | 1489篇 |
1997年 | 936篇 |
1996年 | 751篇 |
1995年 | 555篇 |
1994年 | 459篇 |
1993年 | 405篇 |
1992年 | 282篇 |
1991年 | 271篇 |
1990年 | 257篇 |
1989年 | 241篇 |
1988年 | 203篇 |
1987年 | 167篇 |
1986年 | 119篇 |
1985年 | 117篇 |
1984年 | 91篇 |
1983年 | 63篇 |
1982年 | 38篇 |
1981年 | 40篇 |
1980年 | 30篇 |
1979年 | 30篇 |
1978年 | 30篇 |
1977年 | 38篇 |
1976年 | 61篇 |
1975年 | 19篇 |
1973年 | 20篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
Deok-Hye Park Yo-Seob Kim Sang-Beom Han Woo-Jun Lee Hak-Joo Lee Yong-Soo Lee Sang-Hyun Moon Kyung-Won Park 《International Journal of Hydrogen Energy》2021,46(43):22499-22507
Electrochemical reactions such as the oxygen evolution reaction (OER), oxygen reduction reaction (ORR), and methanol oxidation reaction (MOR) are essential for energy conversion applications such as water electrolysis and fuel cells. Furthermore, Pt or Ir-related materials have been extensively utilized as electrocatalysts for the OER, ORR, and MOR. To reduce the utilization of precious metals, innovative catalyst structures should be proposed. Herein, we report a bi-metallic phosphide (Ni2P and PdP2) structure surrounded by graphitic carbon (Ni–Pd–P/C) with an enhanced electrochemical activity as compared to conventional electrocatalysts. Despite the low Pd content of 3 at%, Ni–Pd–P/C exhibits a low overpotential of 330 mV at 10 mA cm?2 in the OER, high specific activity (2.82 mA cm?2 at 0.8 V) for the ORR, and a high current density of 1.101 A mg?1 for the MOR. The superior electrochemical performance of Ni–Pd–P/C may be attributed to the synergistic effect of the bi-metallic phosphide structure and core-shell structure formed by graphitic carbon. 相似文献
92.
Yerim Kang Sung Min Cho Dong Kyu Kim 《International Journal of Hydrogen Energy》2021,46(13):9174-9185
A lightweight type 4 vessel with a polyethylene terephthalate (PET) liner is analyzed. The derived heat transfer coefficients between the gas and wall are applied, and a parametric study is performed. An optimized charging strategy is also developed. Firstly, when the injected hydrogen temperature decreases, the charging time increases, and the charged gas temperature decreases. Secondly, the higher the ambient temperature, the shorter the charging time, and the higher the charged gas temperature. Thirdly, the larger the mass flow rate, the shorter the charging time, and the higher charged gas temperature. Fourthly, as the initial pressure inside the vessel increases, the charging time shortens, and the charged gas temperature decreases. Fifthly, using the formulated charging strategy, during summer, the charged gas temperature decreases by approximately 9 °C. In winter, the charging time is reduced by approximately 58 s. The results provide important information of temperature control for ensuring vessel safety. 相似文献
93.
Yang Jisoo Kim Junghoon Choi Young Jin Hahn Jungwoo 《Food science and biotechnology》2021,30(10):1331-1338
Food Science and Biotechnology - In this study, we prepared hydrocolloid gels in which flaxseed gum (FSG), konjac glucomannan (KGM), and agar (AG) were blended in different ratios for use as a... 相似文献
94.
95.
In this study,the permeabilities of Berea and Otway sandstones were measured under different confining pressures,and porosity was investigated through mercury intrusion porosimetry(MIP).The total porosities of the Berea and Otway sandstones were approximately 17.4%and 25%,respectively.Pore size distributions of each sandstone were almost the same,but the pores in the Otway sandstone were slightly narrower.However,the permeability of the Otway sandstone was smaller than that of the Berea sandstone by one order of magnitude.Three-dimensional(3D)void geometry and geometrical properties of the void spaces relevant to flow were compared to obtain the relation between the permeability differences and porosities of the two sandstones.The 3D geometrical analysis using microfocus X-ray computed tomography(CT)was performed,and the pore geometries of both sandstones were compared using the 3D medial axis(3DMA)method.Pore and throat radii,pore coordination number,tortuosity,number of connecting paths,connecting path volume,and other factors were determined using 3DMA.The Otway sandstone was characterized by a small effective throat/pore radius ratio.Based on the fluid flow mechanism,the lower effective throat/pore radius ratio results in a lower permeability induced by the fluid energy loss,which means that the 3D geometrical shape of void spaces affects the permeability value. 相似文献
96.
97.
98.
Sung Hyun Hwang Soon Ki Kim Jun-Tae Nam Jong-Sung Park 《International Journal of Hydrogen Energy》2021,46(1):1076-1084
Composite anodes of nano-sized Ni and Ba(Zr0.85Y0.15)O3-δ (BZY) were fabricated by infiltrating a single precursor solution of BZY and Ni into the BZY scaffold, and decreasing the calcination temperature to 1173 K. This decrease in the fabrication temperature of the Ni-cermet anode prevents the chemical reaction between the electrolyte and nickel, thus preventing a reduction in the conductivity of the electrolyte. By optimizing the amount of Ni in the Ni-cermet and infiltrating additional catalysts such as CeO2 and Pd, the non-ohmic ASR of the Ni-cermet anode could be optimized. This resulted in a smaller non-ohmic ASR of anode than one that was fabricated by the conventional co-sintering method. Consequently, a high power density of 790 mW/cm2 at 973 K can be obtained from electrolyte-supported cells. 相似文献
99.
In Seop Lim Jin Young Park Eun Jung Choi Min Soo Kim 《International Journal of Hydrogen Energy》2021,46(2):2543-2554
The temperature of a fuel cell has a considerable impact on the saturation of a membrane, electrochemical reaction speed, and durability. So thermal management is considered one of the critical issues in polymer electrolyte membrane fuel cells. Therefore, the reliability of the thermal management system is also crucial for the performance and durability of a fuel cell system. In this work, a methodology for component-level fault diagnosis of polymer electrolyte membrane fuel cell thermal management system for various current densities is proposed. Specifically, this study suggests fault diagnosis using limited data, based on an experimental approach. Normal and five component-level fault states are diagnosed with a support vector machine model using temperature, pressure, and fan control signal data. The effects of training data at different operating current densities on fault diagnosis are analyzed. The effects of data preprocessing method are investigated, and the cause of misdiagnosis is analyzed. On this basis, diagnosis results show that the proposed methodology can realize efficient component-level fault diagnosis using limited data. The diagnosis accuracy is over 92% when the residual basis scaling method is used, and data at the highest operating current density is used to train the support vector machine. 相似文献
100.
Juliana M. Guedes-Oliveira Yuan H. Brad Kim Carlos A. Conte-Junior 《International Journal of Food Science & Technology》2021,56(12):6157-6170
In recent years, much attention has been paid to the consumption of meat and processed meat, and their relationship with a healthy diet. This review provides an overview of the potential strategies, which can be used to provide the implications for producing healthy, wholesome and consistently high-quality meat products. Genetic selection, nutrition and feeding management, and gene manipulation techniques have been used as the main strategies to induce beneficial changes in meat and meat composition. Besides, the incorporation of ingredients that play a technological role and are potentially health-enhancing, such as fibre, fat substitutes, natural antioxidants and the reduction of sodium and nitrites, has a high potential in the development of healthier meat products. In this review, we have observed that many strategies have been successfully used to obtain products with low fat, reduced sodium and nitrite content, low cholesterol and absence of synthetic antioxidants. Another point to be highlighted is that some of these strategies also allow obtaining products with positive health effects that can be potential alternatives to improve consumer acceptance. 相似文献